If your goal is automated plugin activation you don’t have to do it via SQL. You could, of course, but why not use functionality that comes with WordPress?
As I mentioned in my comment, the data has been serialized so you just have to
- unserialize the data,
- add your plugin,
- re-serialize the data,
- and update the option.
Here is a code snippet for that:
$active_plugins = unserialize(get_option('active_plugins'));
if ($active_plugins && is_array($active_plugins)) {
$active_plugins[] = 'PLUGIN-DIR/PLUGIN-FILE.php'; // as in 'akismet/akismet.php'
update_option('active_plugins', serialize($active_plugins));
} else {
// something went wrong...
}