You’re doing it wrong. get_currentuserinfo() returns the data into some preset global variables. Try this:
function outta_here() {
global $user_ID;
get_currentuserinfo();
wp_delete_user($user_ID);
}
add_action( 'wpcf7_before_send_mail', 'outta_here' );
You can read more about get_currentuserinfo() on WP Codex.