A fast and short solution would be –
function wpse_list_pages( $output ){
$output = preg_replace( '/<a(.*?)>(.*?)<\/a>/', '<a$1 title="$2">$2</a>', $output);
return $output;
}
add_filter('wp_list_pages', 'wpse_list_pages');
And if you want a proper way, you could extend Walker_Page
(ref: post-template.php) class and set the Pages Widget walker to class with widget_pages_args
hook