What you are doing is not a valid way of retrieving and checking serialize data from the WP. You may insert array as a user meta but this array behind the scenes is transformed to serialize string something the MySql can handle.
There are options for searching with the LIKE operator but I don’t endorse this use as it can lead to unexpected results.
$args = array(
'number' => 1,
'count_total' => false,
'fields' => 'ID',
'meta_query' => array(
array(
'key' => 'user_biodata',
'value' => 'yourValue',
'compare' => 'LIKE',
),
),
);
$users = get_users($args);