There is a list of roles in the $wp_roles
WordPress global object.
Set $wp_roles
to a global at the top of your method of function:
global $wp_roles;
Use a Select Field to populate the options:
array(
'id' => $prefix . 'role',
'name' => 'Role',
'type' => 'select',
'use_ajax' => false,
'options' => $wp_roles->get_names(),
),
Note: I didn’t install Humanmade CMB to test this code.