Use a ternary operation to keep it trim.
array(
'key' => 'rob_value',
'value' => $rob,
'compare' => ( empty( $rob ) ? '!=' : '=' )
);
Breakdown, incase you’ve not seen ternary operators before..
array(
'key' => 'rob_value',
'value' => $rob,
'compare' => (
// If
empty( $rob )
// Then
? '!='
// Else
: '='
)
);
http://php.net/manual/en/language.operators.comparison.php
FYI: This question should ideally have been on StackOverflow, it’s more centric to general PHP(if/else/comparison) than to WordPress(you just happening to be writing code for WordPress).
All the same, hope that helps..