You need the local path to add an attachment:
// add the file to the media library
$attachment = array(
'post_mime_type' => 'image/png' // the MIME type
, 'post_title' => 'Attachment title'
);
// Adds the file to the media library and generates the thumbnails.
$attach_id = wp_insert_attachment( $attachment, $path ); // PATH!