Yes.
get_post_meta()
uses get_metadata()
which in turn uses update_meta_cache()
to retrieve the values. In the source code we see this part (comment mine)
// $id_column is 'meta_id'
$meta_list = $wpdb->get_results( "SELECT $column, meta_key, meta_value FROM $table WHERE $column IN ($id_list) ORDER BY $id_column ASC", ARRAY_A );
So the meta values will be ordered by meta_id
in ascending order. Meaning, as @Jacob Peattie pointed out in comments, they will be ordered by the date they were added.