Create custom url which executes code (not render render a WordPress entity)?

You can achieve this with a rewrite rule, you just need to exit execution before the main query is run.

First, add a query var that will get set by the rewrite rule:

function wpd_query_vars( $query_vars ){
    $query_vars[] = 'my_var';
    return $query_vars;
}
add_filter( 'query_vars', 'wpd_query_vars' );

Next, the rewrite rule:

function wpd_rewrite_rule(){
    add_rewrite_rule(
        '^my-url/?$',
        'index.php?my_var=true',
        'top'
    );
}
add_action( 'init', 'wpd_rewrite_rule' );

Lastly, we hook parse_request and check for our custom var, run our code, and exit:

function wpd_parse_request( &$wp ){
    if ( array_key_exists( 'my_var', $wp->query_vars ) ){
        echo 'do something';
        exit;
    }
    return;
}
add_action( 'parse_request', 'wpd_parse_request' );

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