How to make 2/3 width column in Gutenberg

You can add a 2 column block layout where 1 block takes up 2 thirds in the block editor using the UI. Adding CSS classes to achieve this is highly unusual and unnecessary

When you add a column block it asks you:

enter image description here

Resulting in column blocks spaced for thirds:

enter image description here

Each block has a percentage width in the block settings:

enter image description here

If you wanted to use the CSS classes from your theme you have several options:

  • Build a custom columns block
  • Add CSS classes to the column blocks, completely override or remove the block CSS and add in your own

It appears you tried to do the latter, and ran into a 100% pure CSS issue, CSS questions are best asked on stackoverflow (they’re offtopic on WPSE as they aren’t WordPress questions)