Check out this page in order to discover your field key for your radio button: http://www.advancedcustomfields.com/docs/functions/get_field_object/
Next, insert this code where you are grabbing your field values:
<?php
$key = 'your_fieldkey_here';
$field = get_field_object($key);
if ($field) {
foreach ($field['choices'] as $key => $value) {
echo ('KEY : ' . $key);
echo ('<br />');
echo ('VALUE : ' . $value);
echo ('<br />');
}
}
?>
This code will return your set of keys and values.
This only issue with this method is that it will not work if your radio button field is inside of a repeater field.