See my answer about spatial and temporal locality.
In particular, arrays are contiguous memory blocks, so large chunks of them will be loaded into the cache upon first access. This makes it comparatively quick to access future elements of the array. Linked lists on the other hand aren’t necessarily in contiguous blocks of memory, and could lead to more cache misses, which increases the time it takes to access them.
Consider the following possible memory layouts for an array data and linked list l_data of large structs
Address Contents | Address Contents
ffff 0000 data[0] | ffff 1000 l_data
ffff 0040 data[1] | ....
ffff 0080 data[2] | ffff 3460 l_data->next
ffff 00c0 data[3] | ....
ffff 0100 data[4] | ffff 8dc0 l_data->next->next
| ffff 8e00 l_data->next->next->next
| ....
| ffff 8f00 l_data->next->next->next->next
If we wanted to loop through this array, the first access to ffff 0000 would require us to go to memory to retrieve (a very slow operation in CPU cycles). However, after the first access the rest of the array would be in the cache, and subsequent accesses would be much quicker. With the linked list, the first access to ffff 1000 would also require us to go to memory. Unfortunately, the processor will cache the memory directly surrounding this location, say all the way up to ffff 2000. As you can see, this doesn’t actually capture any of the other elements of the list, which means that when we go to access l_data->next, we will again have to go to memory.