Will wordpress tools import do everything I need to copy one site to another

On the Tools > Export page it says:

This format, which we call WordPress eXtended RSS or WXR, will contain your posts, pages, comments, custom fields, categories, and tags.

So this will not be sufficient option for you. You need to migrate the database and that requires updating links to reflect the new domain and file structure.

You can migrate the site manually or use one of many plugins dedicated to this job.

If you want to move just the users to the new fresh installation follow this guide.

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