Custom CSS for plugin form

you can check with the_posts hook if your shortcode exists and only enqueue the style if so :

function check_for_shortcode($posts) {
    if ( empty($posts) )
        return $posts;

    $found = false;

    foreach ($posts as $post) {
        if ( stripos($post->post_content, '[CHANGE_TO_YOUR_SHORT_CODE') )
            $found = true;
            break;
        }

    if ($found){
        $url = get_bloginfo( 'template_directory' );
        wp_enqueue_style( 'my_login_Stylesheet',$url.'/my_login_Stylesheet.css' );

    }
    return $posts;
}
add_action('the_posts', 'check_for_shortcode');