Delete duplicate rows from wordpress database where a column is duplicate in phpmyadmin

if you want to keep the row with the lowest id value:

DELETE n1 FROM table n1, table n2 WHERE n1.id > n2.id AND n1.meta_key = n2.meta_key

OR if you want to keep the row with the highest id value:

DELETE n1 FROM table n1, table n2 WHERE n1.id < n2.id AND n1.meta_key= n2.meta_key