filedialog, tkinter and opening files

The exception you get is telling you filedialog is not in your namespace. filedialog (and btw messagebox) is a tkinter module, so it is not imported just with from tkinter import *

>>> from tkinter import *
>>> filedialog
Traceback (most recent call last):
  File "<interactive input>", line 1, in <module>
NameError: name 'filedialog' is not defined
>>> 

you should use for example:

>>> from tkinter import filedialog
>>> filedialog
<module 'tkinter.filedialog' from 'C:\Python32\lib\tkinter\filedialog.py'>
>>>

or

>>> import tkinter.filedialog as fdialog

or

>>> from tkinter.filedialog import askopenfilename

So this would do for your browse button:

from tkinter import *
from tkinter.filedialog import askopenfilename
from tkinter.messagebox import showerror

class MyFrame(Frame):
    def __init__(self):
        Frame.__init__(self)
        self.master.title("Example")
        self.master.rowconfigure(5, weight=1)
        self.master.columnconfigure(5, weight=1)
        self.grid(sticky=W+E+N+S)

        self.button = Button(self, text="Browse", command=self.load_file, width=10)
        self.button.grid(row=1, column=0, sticky=W)

    def load_file(self):
        fname = askopenfilename(filetypes=(("Template files", "*.tplate"),
                                           ("HTML files", "*.html;*.htm"),
                                           ("All files", "*.*") ))
        if fname:
            try:
                print("""here it comes: self.settings["template"].set(fname)""")
            except:                     # <- naked except is a bad idea
                showerror("Open Source File", "Failed to read file\n'%s'" % fname)
            return


if __name__ == "__main__":
    MyFrame().mainloop()