Assuming
– you saved the post in the “quote” type
– you actually set and save a “who” meta for those post
– you forgot to paste the close section of the loop,
as s_ha_dum stated, your code should work.
Like this
<div id="introBottom" class="group">
<?php
$quote_args = array(
'post_type' => 'post',
'category' => 'quote',
'orderby' => 'rand',
'posts_per_page' => 1
);
$quote = new WP_Query($quote_args);
if($quote->have_posts()):
while($quote->have_posts()):
$quote->the_post();
?>
<p id="testimonial">
<?php echo the_content(); ?>
<span><?php echo get_post_meta($post->ID, 'who', true); ?></span>
</p>
<?php
endwhile;
endif;
?>
</div>