SQLSTATE[HY093]: Invalid parameter number: parameter was not defined

This error you are receiving:

SQLSTATE[HY093]: Invalid parameter number: parameter was not defined

is because the number of elements in $values & $matches is not the same or $matches contains more than 1 element.

If $matches contains more than 1 element, then the insert will fail, because there is only 1 column name referenced in the query(hash)

If $values & $matches do not contain the same number of elements then the insert will also fail, due to the query expecting x params but it is receiving y data $matches .

I believe you will also need to ensure the column hash has a unique index on it as well.

Try the code here:

<?php

/*** mysql hostname ***/
$hostname = 'localhost';

/*** mysql username ***/
$username = 'root';

/*** mysql password ***/
$password = '';

try {
    $dbh = new PDO("mysql:host=$hostname;dbname=test", $username, $password);
    /*** echo a message saying we have connected ***/
    echo 'Connected to database';
    }
catch(PDOException $e)
    {
    echo $e->getMessage();
    }

  
$matches = array('1');
$count = count($matches);
for($i = 0; $i < $count; ++$i) {
    $values[] = '?';
}

// INSERT INTO DATABASE
$sql = "INSERT INTO hashes (hash) VALUES (" . implode(', ', $values) . ") ON DUPLICATE KEY UPDATE hash='hash'";
$stmt = $dbh->prepare($sql);
$data = $stmt->execute($matches);

//Error reporting if something went wrong...
var_dump($dbh->errorInfo());

?>

You will need to adapt it a little.

Table structure I used is here:

CREATE TABLE IF NOT EXISTS `hashes` (
  `hashid` int(11) NOT NULL AUTO_INCREMENT,
  `hash` varchar(250) NOT NULL,
  PRIMARY KEY (`hashid`),
  UNIQUE KEY `hash1` (`hash`)
) ENGINE=InnoDB  DEFAULT CHARSET=latin1 AUTO_INCREMENT=1 ;

Code was run on my XAMPP Server which is using PHP 5.3.8 with MySQL 5.5.16.