Using a comparator function to sort

You’re passing the comparator as the key function. You should be passing it as the cmp, wrapped in some kind of function that turns it into a proper comparator.

def make_comparator(less_than):
    def compare(x, y):
        if less_than(x, y):
            return -1
        elif less_than(y, x):
            return 1
        else:
            return 0
    return compare

sortedDict = sorted(subjects, cmp=make_comparator(cmpValue), reverse=True)

(Although actually, you should be using key functions:

sorted(subjects, operator.itemgetter(0), reverse=True)

Also note that sortedDict will not actually be a dict, so the name is rather confusing.)