Just call woocommerce proceed-to-checkout-button template in woocommerce_before_cart action hook as follows-
add_action('woocommerce_before_cart', 'add_wc_button_proceed_to_checkout');
function add_wc_button_proceed_to_checkout(){
echo '<div class="wc-proceed-to-checkout">';
wc_get_template( 'cart/proceed-to-checkout-button.php' );
echo '</div>';
}