Yes, you can add additional email to receive mail from woo commerce. Here you can find out more detail : https://wordpress.stackexchange.com/questions/92020/adding-a-second-email-address-to-a-completed-order-in-woocommerce
Reply By Email to comment notifications
Once you know how all your site-generated mail is being sent, you can set up your DNS records to help validate it. AWeber is not using WordPress or your server. The SPF record you attached to your domain for use with AWeber tells mailservers that email associated with your domain may actually originate from aweber.com. … Read more
The template you need to override sits on this path woocommerce/templates/emails/admin-new-order.php This template can be overridden by copying it to yourtheme/woocommerce/emails/admin-new-order.php. You can put your code there and this code will be executed for all the recipients that have been configured through the backend by going to Woocommerce > Settings > Emails > New order … Read more
I never did get this to work, as a work around I had to configure the WP-SMTPMail to send directly to our Office365 instance, which required an additional user to be configured.
I managed to do so using a plugin called IP2Location Redirection, then it worked well for me. It turned out that Geo Redirect hasn’t been compatible with latest versions of WordPress.
User registration email and let user choose pasword
Send multiple attachments with wp_mail in PHP
How to send mail from WordPress if one server hosts page and another email?
Sending HTML emails via wp_mail not working properly