ValueError : I/O operation on closed file

Indent correctly; your for statement should be inside the with block:

import csv    

with open('v.csv', 'w') as csvfile:
    cwriter = csv.writer(csvfile, delimiter=' ', quotechar='|', quoting=csv.QUOTE_MINIMAL)

    for w, c in p.items():
        cwriter.writerow(w + c)

Outside the with block, the file is closed.

>>> with open('/tmp/1', 'w') as f:
...     print(f.closed)
... 
False
>>> print(f.closed)
True