Getting Different Size Of Attachment Images

Since you have defined the featured image for each post with using

<?php the_post_thumbnail( 'custombig' ); // or another custom size name ?>

should be enough, for info you can read:

http://justintadlock.com/archives/2009/11/16/everything-you-need-to-know-about-wordpress-2-9s-post-image-feature

http://markjaquith.wordpress.com/2009/12/23/new-in-wordpress-2-9-post-thumbnail-images/

Or here there is good info too:

How wordpress handle upload images and how to use them in the code

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