TypeError: ‘float’ object is not subscriptable

PriceList[0] is a float. PriceList[0][1] is trying to access the first element of a float. Instead, do

PriceList[0] = PriceList[1] = ...code omitted... = PriceList[6] = PizzaChange

or

PriceList[0:7] = [PizzaChange]*7