One way or another you must tell boto3 in which region you wish the kms client to be created. This could be done explicitly using the region_name parameter as in:
kms = boto3.client('kms', region_name='us-west-2')
or you can have a default region associated with your profile in your ~/.aws/config file as in:
[default] region=us-west-2
or you can use an environment variable as in:
export AWS_DEFAULT_REGION=us-west-2
but you do need to tell boto3 which region to use.
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