Python how to write to a binary file?

This is exactly what bytearray is for:

newFileByteArray = bytearray(newFileBytes)
newFile.write(newFileByteArray)

If you’re using Python 3.x, you can use bytes instead (and probably ought to, as it signals your intention better). But in Python 2.x, that won’t work, because bytes is just an alias for str. As usual, showing with the interactive interpreter is easier than explaining with text, so let me just do that.

Python 3.x:

>>> bytearray(newFileBytes)
bytearray(b'{\x03\xff\x00d')
>>> bytes(newFileBytes)
b'{\x03\xff\x00d'

Python 2.x:

>>> bytearray(newFileBytes)
bytearray(b'{\x03\xff\x00d')
>>> bytes(newFileBytes)
'[123, 3, 255, 0, 100]'