Super admins do have access to all sites, but they don’t show up in “My Sites” by default, which I imagine is where you’re looking. They’ll want to go to the network admin (/wp-admin/network/, then go to all sites from there, then find the site they want to edit and click “Dashboard” (which appears on hover).
I like to think of “My Sites” almost as favorites, and only add myself to a site when I’ll be accessing it frequently, as it reduces the list I have to pick through.
Does that make sense and clear up your question?
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